The 25.4mm/in (2.54cm/in) becomes the first thing you really hang onto in real world engineering. It's the bane of the machinist though.
Often times when talking about fits and tolerances the 0.4 gets dropped so that 25 microns (0.025mm)= 1 thousandth of an inch (0.001"). That makes for easy conversions for those stuck in thinking about machine tolerances in inches.
I still do the conversion all the time because my brain thinks of size in inches like many people brought up on English units. But once you do something all the time in SI it gets to the point where you think of things in mm. It still doesn't always have a good tie to reality though... same goes for Newtons of force. That's all we use these days but if I need to relate it to myself I need to convert it to pounds and relate it to my own weight, or the weight of my boat, or something familiar.